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Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication

Received: 21 February 2019     Accepted: 4 April 2019     Published: 6 May 2019
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Abstract

A Blend of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C60-butyric acid methyl ester (PCBM), a fullerene derivate based donor-acceptor copolymer, is one of the widely used organic solar cell materials for photon-electron conversion. Thin films were developed, characterized, and optimized for optical absorbance. Absorption spectra were measured using a UV-VIS spectrophotometer. In this work, the effects of composition ratios of P3HT:PC60BM and various thicknesses was studied in ambient conditions. The P3HT:PC61BM thin film was deposited in two different composition ratio (1:1 and 1:3) and fabricated at seven different thicknesses of 20 nm, 30 nm, 35 nm, 87 nm, 98 nm, 115 nm, and 146 nm corresponding to spin coating speeds of 4000rpm, 3000rpm, 2000rpm, 1500rpm, 1250rpm, 1000rpm, and 750rpm, respectively. P3HT:PC60BM thin film composition ratio of 1:1 with thickness of 87nm shows relatively better photon absorption optical parameter than P3HT:PC60BM composition ratio of 1:3. P3HT: PC61BM solution coated at a spin speed of 1500 rpm shows a better absorption of photon energy. The results showed that the optimum thickness of the thin film is 87 nm at composition ratio of 1:1. Energy band gap values of composition ratio of 1:3 is observed to decreases with increase in spin- speed from 3.9 eV to 3.7 eV. The results can be used as a guideline for improving the design and fabrication of active layer of organic solar cells.

Published in Journal of Photonic Materials and Technology (Volume 5, Issue 1)
DOI 10.11648/j.jmpt.20190501.12
Page(s) 5-10
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Optical Transmittance, Reflectance, Absorbance, Organic Thin Film, P3HT, PCBM Blend, Bandgap Energy

References
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[8] Shang-ChouChang, Yu-JenHsiao, To-SingLi (2013). P3HT:PCBM Incorporated with Silicon Nanoparticles as Photoactive Layer in Efficient Organic Photovoltaic Devices Hindawi Publishing Corporation J Nanomaterials Volume 2013,ArticleID354035,4pages http: //dx.doi.org/10.1155/2013/3.
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    Sunday Wilson Balogun, Yekini Kolawole Sanusi. (2019). Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication. Journal of Photonic Materials and Technology, 5(1), 5-10. https://doi.org/10.11648/j.jmpt.20190501.12

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    ACS Style

    Sunday Wilson Balogun; Yekini Kolawole Sanusi. Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication. J. Photonic Mater. Technol. 2019, 5(1), 5-10. doi: 10.11648/j.jmpt.20190501.12

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    AMA Style

    Sunday Wilson Balogun, Yekini Kolawole Sanusi. Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication. J Photonic Mater Technol. 2019;5(1):5-10. doi: 10.11648/j.jmpt.20190501.12

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  • @article{10.11648/j.jmpt.20190501.12,
      author = {Sunday Wilson Balogun and Yekini Kolawole Sanusi},
      title = {Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication},
      journal = {Journal of Photonic Materials and Technology},
      volume = {5},
      number = {1},
      pages = {5-10},
      doi = {10.11648/j.jmpt.20190501.12},
      url = {https://doi.org/10.11648/j.jmpt.20190501.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jmpt.20190501.12},
      abstract = {A Blend of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C60-butyric acid methyl ester (PCBM), a fullerene derivate based donor-acceptor copolymer, is one of the widely used organic solar cell materials for photon-electron conversion. Thin films were developed, characterized, and optimized for optical absorbance. Absorption spectra were measured using a UV-VIS spectrophotometer. In this work, the effects of composition ratios of P3HT:PC60BM and various thicknesses was studied in ambient conditions. The P3HT:PC61BM thin film was deposited in two different composition ratio (1:1 and 1:3) and fabricated at seven different thicknesses of 20 nm, 30 nm, 35 nm, 87 nm, 98 nm, 115 nm, and 146 nm corresponding to spin coating speeds of 4000rpm, 3000rpm, 2000rpm, 1500rpm, 1250rpm, 1000rpm, and 750rpm, respectively. P3HT:PC60BM thin film composition ratio of 1:1 with thickness of 87nm shows relatively better photon absorption optical parameter than P3HT:PC60BM composition ratio of 1:3. P3HT: PC61BM solution coated at a spin speed of 1500 rpm shows a better absorption of photon energy. The results showed that the optimum thickness of the thin film is 87 nm at composition ratio of 1:1. Energy band gap values of composition ratio of 1:3 is observed to decreases with increase in spin- speed from 3.9 eV to 3.7 eV. The results can be used as a guideline for improving the design and fabrication of active layer of organic solar cells.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Effect of Thickness and Composition Ratio of Poly(3-Hexylthiophene) and [6,6]-Phenyl C60-Butyric Acid Methyl Ester Thin Film on Optical Absorption for Organic Solar Cell Fabrication
    AU  - Sunday Wilson Balogun
    AU  - Yekini Kolawole Sanusi
    Y1  - 2019/05/06
    PY  - 2019
    N1  - https://doi.org/10.11648/j.jmpt.20190501.12
    DO  - 10.11648/j.jmpt.20190501.12
    T2  - Journal of Photonic Materials and Technology
    JF  - Journal of Photonic Materials and Technology
    JO  - Journal of Photonic Materials and Technology
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    EP  - 10
    PB  - Science Publishing Group
    SN  - 2469-8431
    UR  - https://doi.org/10.11648/j.jmpt.20190501.12
    AB  - A Blend of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C60-butyric acid methyl ester (PCBM), a fullerene derivate based donor-acceptor copolymer, is one of the widely used organic solar cell materials for photon-electron conversion. Thin films were developed, characterized, and optimized for optical absorbance. Absorption spectra were measured using a UV-VIS spectrophotometer. In this work, the effects of composition ratios of P3HT:PC60BM and various thicknesses was studied in ambient conditions. The P3HT:PC61BM thin film was deposited in two different composition ratio (1:1 and 1:3) and fabricated at seven different thicknesses of 20 nm, 30 nm, 35 nm, 87 nm, 98 nm, 115 nm, and 146 nm corresponding to spin coating speeds of 4000rpm, 3000rpm, 2000rpm, 1500rpm, 1250rpm, 1000rpm, and 750rpm, respectively. P3HT:PC60BM thin film composition ratio of 1:1 with thickness of 87nm shows relatively better photon absorption optical parameter than P3HT:PC60BM composition ratio of 1:3. P3HT: PC61BM solution coated at a spin speed of 1500 rpm shows a better absorption of photon energy. The results showed that the optimum thickness of the thin film is 87 nm at composition ratio of 1:1. Energy band gap values of composition ratio of 1:3 is observed to decreases with increase in spin- speed from 3.9 eV to 3.7 eV. The results can be used as a guideline for improving the design and fabrication of active layer of organic solar cells.
    VL  - 5
    IS  - 1
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Author Information
  • Department of Materials Science and Engineering Laboratory, Kwara State University Malete, Ilorin, Nigeria

  • Department of Materials Science and Engineering Laboratory, Kwara State University Malete, Ilorin, Nigeria

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